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http://volcanology.geol.ucsb.edu/gas.htm
Sulfur Dioxide
The greatest volcanic impact upon the earth's short term weather patterns is caused by sulfur dioxide gas. In the cold lower atmosphere, it is converted to sulfuric acid by the sun's rays reacting with stratospheric water vapor to form sulfuric acid aerosol layers. The aerosol remains in suspension long after solid ash particles have fallen to earth and forms a layer of sulfuric acid droplets between 15 to 25 kilometers up. Fine ash particles from an eruption column fall out too quickly to significantly cool the atmosphere over an extended period of time, no matter how large the eruption.
Sulfur aerosols last many years, and several historic eruptions show a good correlation of sulfur dioxide layers in the atmosphere with a decrease in average temperature decrease of subsequent years. The close correlation was first established after the 1963 eruption of Agung volcano in Indonesia when it was found that sulfur dioxide reached the stratosphere and stayed as a sulfuric acid aerosol.
Without replenishment, the sulfuric acid aerosol layer around the earth is gradually depleted, but it is renewed by each eruption rich in sulfur dioxide. This was confirmed by data collected after the eruptions of El Chichon, Mexico (1982) and Pinatubo, Philippines (1991), both of which were high-sulfur compound carriers like Agung, Indonesia.
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